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Alexandra Kirilova


Alexandra Kirillova Faculty: Faculty of mountain (FM)
Specialty: "Forcefield Security of employment"
Group: BTD – 11m
Master's thesis topic: Justification of the parameters of non-explosive rock breaking self-expanding compounds, preventing them from spontaneous emission of holes in the process of hydration
Scientific adviser: Ph.D., Ivan Sakhno

Resume

Abstract

1 A rationale and relevance of the topic

               In the modern practice of mining quarries, coal mines, in most cases used drilling and blasting method of rock breaking, one of the shortcomings of which is a dynamic impact on the breed and their softening. However, despite the progress made in managing the explosive destruction through the creation and use of special construction charges, one of the most pressing problems is the high yield of sub-standard units, which are mainly the elimination of overhead charges are explosive. The destruction of oversized blocks in underground mine workings of coal mines is carried out either by mechanical means using hand tools or as cumulative patch charges. At the same time keeping blasting dust and gas often limited regime, and the use of mechanized methods – the strength of rocks. An alternative to solve this and other tasks would be to use non-explosive depleting substances (NRW), the use of which is enough tested in the construction industry in the destruction of the bearing elements of buildings and structures. (fig. 1) The widespread introduction of non-explosive destruction technology constrained the complexity of their implementation in the real world, because the behavior of NRW with fluctuations in temperature, humidity, the ratio of incoming components, the degree of mixing can be significantly altered. Thus, for example, lowering the temperature of the environment leads to a decrease in the rate of hydration and the pressure developed by samorasshireniya [1], which reduces the effectiveness of non-explosive destruction. Raising the temperature of the environment contributes to the contrary the rate of hydration reaction [2], and since the reaction is exothermic, it often leads to involuntary release of HPB from the hole. Thus, the question now developing a method for non-explosive rock breaking with a decrease in the likelihood of inadvertent release of a mixture of the hole quite relevant.

    The destruction of the material with NRV 80

    Figure 1 – The destruction of the material with NRV 80


2 Aims and objectives of the study

              Purpose – study the parameters of rock with the LDCs, with the exception of their ejection from the holes in the process of hydration. The idea of work – is to ensure the stabilization of the thermokinetic process of hydration of calcium oxide at room charge of LDCs shpurovye and borehole charges (fig. 2). The problems solved in the master's work: 1. A. Laboratory studies of patterns of temperature change sotava LDCs in the process of hydration in shpurovyh and borehole charges. Develop ways to stabilize the temperature of the LDCs in terms of the hole while reducing the time of rock. Defining the parameters of the developed method and laboratory tests. The object of study – rockmass accommodates the charge of LDCs. The subject of research – the process of rock with the LDCs. Research Methods – Mathematical modeling, physical modeling method, the method of statistical processing of data.

    Results of the destruction of the gypsum board by means of explosives and using the NRW-80

    Figure 2 – Results of the destruction of the gypsum board by means of explosives and using the NRW-80


3 Scientific novelty and practical value of

          – The scientific novelty of the work is as follows: – Established patterns of temperature change of the LDCs in terms of shpurovyh and borehole charges in various stages of hydration.
          – Experimental dependence obtained for the calculation (fig. 3) of fracture parameters of rocks in the LDCs shpurovyh and borehole charges of large diameter.

Destruction of the concrete

Figure 3 – Destruction of the concrete


4 Review of existing research and development on the subject

              Currently, the undisputed leader of the destruction of solid rock in the development of mineral deposits as open and underground drilling and blasting is the way. The main disadvantage of this method is a seismic impact of the explosion on the rock, a violation of their continuity, the development of cracks and weakening of the array. The most acute when it affects mining gems and kristallosyrya, block materials, delineating mining. Application nizkobrizantnyh explosive rounds and charges of special designs can reduce the dynamic impact on okoloshpurovuyu area, but their use leads to higher costs for demolition and in some cases does not provide the desired outcomes. For example, the extraction of a block of stone losses reach 40% or more.
              One possible solution to this problem is to use static methods of rock. There are currently many non-explosive methods of destruction, in particular, mechanical methods (wedge, gidroklinovoy, diamond rope sawing, drilling and stone cutting harvesters), methods based on the energy of the fluid (hydrodynamic, physico–chemical impulse break, hammer, waterjet cutting, flyuidorazryv) , thermal (termorezka), electrical and electromagnetic (blowing of electrical conductors, electrical breakdown, thermal breakdown, a high-frequency currents, melting, laser radiation, electromagnetic radiation), the combined methods. Most of these methods are under research and development work. Their industrial use is hampered by lack of equipment, low reliability, high energy, risk of human exposure, high cost. All these disadvantages forced to look for ways to create inexpensive and promising means of destruction solid rock.Starting from 1980 till now only in Japan has developed more than two dozen non-explosive destructive compounds for practical application in open and underground facilities [3, 4]. Almost simultaneously, the State All-Union Scientific Research Institute of Building and wall constructions to them. PP Budnikova proposed several non-explosive depleting compounds [5, 6]. Today in the developed world, more than 100 different compositions of LDCs. Their main disadvantage is long compared to the time of drilling and blasting method of destruction (824), a limited operating temperature. At subzero temperatures dramatically reduces the efficiency of destruction by slowing the rate of hydration, and positive at high temperatures observed neprizvolnoe ejection of a mixture of LDCs in the holes caused by the sharp increase in the rate of hydration. The reason for the ejection of a mixture of the LDCs is the growth of holes vnutrishpurovogo vapor – gas pressure, rising sharply at the transition of chemically unbound water in the steam at a temperature exceeding the LDCs in the process of hydration, the temperature of boiling water.
              Recently, the Donetsk National Technical University is working to expand the scope of the LDCs, in particular the use of temperature fields in underground mine workings. The main task is to reduce the time of destruction and exclusion of both the phenomenon of spontaneous emission of LDCs from the hole.
           To solve this problem, the authors carried out comprehensive studies of the kinetics of samorasshireniya LDCs, based on calcium oxide (fig. 4).
            The studies identified specific stages of the LDCs and their characteristics are given [7] identified the growth pressure dependence samorasshireniya with different mode of operation [8].
             Analysis of the patent literature shows that the speed control of the hydration reaction is carried out by the addition of accelerators, retarders, and plasticizers. Adding accelerators are mainly recommended for the destruction of materials at low temperatures and their effect in most cases it boils down to an additional increase in temperature of the liquid mixture in the solution phase LDCs, due to the strong reaction of the accelerator ekzotermichekoy with calcium oxide. Adding moderators to produce a stabilization rate of hydration at high positive temperatures, thus preventing unintentional ejection of a mixture of holes, but the destruction of the materials increases. Effect of plasticizers generally is to improve the mobility of a mixture of LDCs.Literature shows that the speed control of the hydration reaction is carried out by the addition of accelerators, retarders, and plasticizers. Adding accelerators are mainly recommended for the destruction of materials at low temperatures and their effect in most cases it boils down to an additional increase in temperature of the liquid mixture in the solution phase LDCs, due to the strong reaction of the accelerator ekzotermichekoy with calcium oxide. Adding moderators to produce a stabilization rate of hydration at high positive temperatures, thus preventing unintentional ejection of a mixture of holes, but the destruction of the materials increases. Effect of plasticizers generally is to improve the mobility of a mixture of LDCs.
              Thus, non-explosive destruction of the existing methods with the help of the LDCs to achieve reduction in the time of destruction of rocks in shpurovyh and large – diameter hole charges, while excluding "vyshpurivaniya" quite difficult. These solutions are currently in the world is not found. So far, studies on the kinetics of growth temperature in the borehole LDC charges have been conducted.

The rate of expansion of the LDCs with a metal insert

Figure 4 – The rate of expansion of the LDCs with a metal insert


5 Current and future results of studies on the topic

          Basic research is the prospect of the use of the work in the coal industry of Ukraine.

Literature

1. A. Pat. UA 59 940, IPC (2006) C04B 7/34, C04B 24/00 Nevibuhova ruyn³vna rechovina NRV-80 / VF Gribko; Scheblik³n SV, AV Paley (Ukraina). – 2002129862; appl. 12/09/2002, publ. 15.07.2005, Bull. Number 7. – 6 s. Ill.
2. Kasian N. Rationale for management growth rate of compression characteristics of spacer-depleting substances non-explosive / Kasian NN, Sakhno IG, Shulyak Ya.O. / / Visti g³rnichogo ³nstitutu of Donetsk. Donetsk – 2010. – ¹ 2. – S. 209-219.
3. Application 57–187044, Japan, MKI C 02 B 19/18. Tool for breaking rock and concrete / Akira Saito, Seiichi Nakatani, Akira Miwa, Isao Agha, Isakaev juku, Denki Kagaku KK coherent, ¹ 56–71233 appl. 12.05.81, publ. 17.11.82.
4. Application 57–136954, Japan, MKI C 02 B 19/18. Means for the destruction of stone materials, including concrete / Akio Nishihara, Miwa Motomu, Tada Syuti; Asahi Denki KK coherent, ¹ 56–23509 appl. 19.02.81, publ. 24.08.82.
5. Nikolaev, MM The new material for the effective destruction of the brittle solid objects / Nikolaev, MM, GV Zakharov, AV Glazunov / / Mining Journal. In 1989. Number 5. – S. 35–36.
6. Non – explosive means of destroying (NRS-1). Specifications, MPSM USSR, 1987, 37.
7. Pat. Number 60 794, IPC (2011.01) G01L 1/10, E21S 37/00 stand for viprobuvan nevibuhovih ruynuyuchih rechovin / M. M Kasian, ².G. Sakhno (Ukraina). – 2010 15412; zayavl. 20.12.2010, publ. 25.06.2011, Bull. Number 12. – 6 s. Ill.
8. AS USSR N 1648911, IPC C 04 B 5 7/00, would destroy the material / Luginin IG, YG Sheremet'ev – 4496506/33, zayavl.19.10.1989, publ. 15.05.1991, Bull. Number 18. – 2 c.

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