Viktoriya Bencharskaya

Faculty of Ecology and Chemical Technologies (FEHT)

Department Cumulative skopaemyh and Environmental Geology

Speciality Environmental Geology

Features technological changes on the landscape mine them. Kalinin and their impact on the ecological environment

Scientific adviser:D.g.s., Professor Victor Alоkhine

Resume Abstract

Abstract final work on the topic

Contents

• Introduction
• Actuality
• Communication with scientific themes, plans
• Objective Studies
• Research tasks
• Research Methods
• Scientific novelty
• Practical Importance
• Personal contribution website
• Testing results
• Publications
• Review and analysis of research on the topic
• Geological characteristics of the object of study
• Ecological characteristics
• Research Methods
• Current and anticipated results
• Conclusions
• References

Introduction

Actuality

Donbass Donetsk coal or pool is one of the largest mining areas in Europe and around the world, where for more than 200 years of industrial development produced over 8mlr.t bituminous coal and anthracite.

For Donetsk-Makeevka area, as for most of the Donbass, one of the main pollutants of the environment is the coal industry. In this regard, the most important is the study of the features of environmental pollution as a result of activity of the enterprises of the industry.

Peculiarity Donbass coal is increased concentration in them of some heavy metals and toxic elements - mercury, arsenic, sulfur, molybdenum, beryllium. Individual brands coals contain higher concentrations as lithium, thallium, scandium and other chemical elements. Significant excess Clarks sedimentary rocks and coals fixed elements I-III Hazard Class: Sb, Pb, V, Cd, Zn, Mo, Li [ 1 ].

Today, the main factors contributing to the spread of particular pollutants, are not only the composition of coals and specificity of the process, but also landscapes of the study area. In landscape components at all levels are formed mechanical and geochemical barriers, where pollutants are concentrated biosphere elements and substances. Study of features of distribution of pollutants in the components of the landscape is an important task in the study area.

Communication with scientific themes, plans

Studies meets state scientific program "Reigning tsіlova ekologіchna programa implement the core monіtoringu navkolishnogo natural seredovischa" (Holds Kabіnetu Mіnіstrіv od of Ukraine 05.12.2007 № 1376).

Job requirements settles a number of regulatory documents: the Law of Ukraine: About receptionists navkolishnogo natural seredovischa od 25.06.91 p. (Stattya 22); Laws of Ukraine: on Waste and protection of land; Resolution of the Cabinet of Ministers of Ukraine dated August 20, 1993, № 661: The provisions of monіtoring land.

The purpose of research

Aim of this work is to assess the technological changes landscape components within the influence of OP "mine them. Kalinin. " Identification of patterns of migration of substances allows to identify the sources of contamination and areas of concentration of pollutants.

Research tasks

1. Synthesis of information as the issue of the literary sources and archival materials.
2. Water sampling and soil data processing analyzes of these samples.
3. Statistical processing of all data.
4. Study the features of migration and spatial distribution of substances in the various components of the landscape - the soils, waters.
5. Identifying links to the study area of mined coal zagryaznyayushimi landscape with chemical elements.

Object of study : Industrial site and the neighborhood mine them. MI Kalinina.

Subject of research : The spatial distribution of pollutants in the landscapes.

Research Methods

1. Analysis of available geological and environmental materials in the area of research.
2. Organizing data chemical composition of mine water and soil.
3. Fieldwork territory with the selection of additional tests.
4. Statistical treatment of geochemical data.
5. Methods of constructing specialized maps, diagrams, etc.

Scientific novelty

1. First for the area were allocated plots of maximum accumulation in soils and subsoils and halos found between pollution and landscape features.
2. Peculiarities influence of mine waters on the change in concentration of a number of substances in the waters of the beam and Ignatievskaya Kalmiusskogo reservoir.
3. The character of the influence of various factors (anthropogenic and natural) to change the composition of discharged water.

Practical Importance

A result of the work of established areas with the strongest soil contamination that would adversely affect the environment of the study area. Revealed laws allow in further studies to justify the depth of sampling. Set the spatial and temporal patterns of change in the composition of water in the chain: mine water to clean - mine water after cleaning - water used. Ignatievskaya - Kalmius river.

Personal contribution website

Were selected, treated water samples of soils at the test site, a detailed analysis of the chemical composition of the mine and surface water, and soil and subsoil on 2 levels deep. Graphs of changes in the concentrations of pollutants in mine waters as their purification according to the season and away from the point of primary relief.

The maps of distribution of substances and elements in soils and soils. Established areas and depth of maximum accumulation of elements.

The effect on the distribution of landscape features of pollutants on the mine.

Testing results

Author participated in the VII International scientific practical conference of students and young scientists Donbass - 2020: The prospects for the development of young scientists through the eyes of a report on "Features of anthropogenic changes in the composition of soil in the field of mine it. MI Kalinina »

Publications

Abstracts on "Features of anthropogenic changes in the composition of soil in the field of mine it. MI Kalinina, "published in the collection of articles VII International scientific practical conference of students and young scientists Donbass - 2020: The prospects for the development of young scientists through the eyes of a report on" Features of anthropogenic changes in the composition of soil in the field of mine it. MI Kalinina, "page 65-69.

Review and analysis of the topic

Research close to the subject of this paper highlights a number of publications.

Volkova TP and VV Falevich [ 2 ] analyzed the impact of coal mining enterprises in the condition of the environment on the example of a mine field mine "Lidievka." Izuchen0 statistically the spatial distribution of elements in soils, conclusions about areas of maximum accumulation of elements.

In "Assessing the impact of a coal mine on the environment» [ 3 ] examined the causes of the ecological crisis on the ground, as a result of the industrialized world. The coal industry will inevitably adversely affect the environment, polluting and violating her. To solve this problem were identified promising clean technology, ecological processes and equipment.

Job "Evaluation negative impact on the nature of the mine» [ 4 ] is devoted to the study of the main sources of pollution of the environment and determine the influence of the activities of the neighborhood of the mine on the example of mine Zasyad'ko.

During studies of the effect of industrial objects observed a significant influence on the formation of halos landscape pollution. Geochemical studies of landscapes are widely used to assess the environmental pollution.

Basic ideas and landscape geochemistry provisions were formulated in a series of brilliant articles 40-50s B.B.Polynovym [ 5 ]. Under the terms of the migration of chemical elements BB Polynov identified three main elementary landscape: eluvial, superaqueous (surface) and subaqueous (underwater). Polynov showed that the migration of chemical elements connects the rocks, soil, living organisms, natural water and the atmosphere, that by studying this migration, we thus we reveal the substance of the relationship between these components of the landscape, we understand it as a whole.

Next this topic evolve in several editions of the textbook "Landscape Geochemistry» [ 6, 7, 8 ]. Were sformultrovany main concepts of science, based on the ideas of VI Vernadsky and BB Polinova: the leading role of living matter in the migration of atoms in the natural landscape and the biosphere as a whole, communication elements geochemistry in the natural landscape and the biosphere as a whole, perceptions of landscape-geochemical systems and geochemical barriers and the impact of these relationships on the migration of man-made substances.

In papers Alexeenko VA [ 9 ] examined the challenges facing this science, including those related to the possible negative consequences of human activities. Theoretical propositions environmental geochemistry outlined in close connection with the practical issues of economic activity. It contains a large number of illustrations.

Malyshev LL in his "Theory and methods of landscape-geochemical analysis and assessment of the environmental condition of the territories» [ 10 ] The technique of landscape - geochemical analysis and assessment of the environmental status of the areas (algorithm criteria system indicators), which was tested in the areas of influence of nuclear power plants, industrial zones, agricultural landscapes, urban landscapes, recreational areas. Classification principles defined the basic types of landscape - geochemical structure.

So the basic principles of landscape ecology applied in practice for all industrial enterprises and allow to identify the main patterns of anthropogenic pollution.

Main patterns of spatial distribution of pollutants discussed in the article "Industrial air emissions - the source of contamination of the soil» [ 11 ]. A brief description of the types of soil degradation due to pollution.

Monograph devoted to the problems of soil in urban areas, the authors NG Fedoretc and MV Medvedev [ 12 ] noted that heavy metals received at the soil surface, accumulate in the soil mass, especially in the upper humus horizons and slowly removed their concentration decreases sharply with depth, and clay minerals contribute to the accumulation of organic matter and.

In his work Medvedev MV, Fedoretc NG, AS Yakovlev [ 13 ] analyzed the characteristics of manmade pollution. Conclusion - the amount of heavy metals in the upper horizon exceeds by several times the amount that is spent on the further transformation of the biota and takeaways in the underlying strata in the various chemical compounds.

literature review showed that many questions anthropogenic landscape changes on the areas of coal mines have not been studied. Especially it concerns the influence of local landscape factors on the concentration of pollutants. Exploration of these factors is devoted to this master's work.

Geological characteristics of the object of research

Stratigraphy and lithology

The geological structure of the field of mine attended deposition suites C₂⁵, C₂⁴ and C₂³ Middle Carboniferous. Stratigraphically overlying strata (Formation C₂⁶, C₂⁷) belongs to the fields of mines them. Zasyad'ko, Krasnogvardeyskaya, Ganzovskaya-2.

Carboniferous deposits are poluskalnyh and rock (monoclinally-seated mudstones and siltstones with rare interbedded limestones), overlain by Quaternary formations represented loess loams and clays up to 15 m and the soil-plant-bed capacity of 0.3-0.5 m

These deposits from the surface of a large territory covered by technogenic soils of different capacities.

Stretch rocks south-west, the fall in the north-west at an angle of 10 degrees. Siltstones greenish-gray, brownish-gray (by impregnation with iron hydroxides in areas of intense fracturing), with mica flakes along the bedding planes. Siltstones uneven fracture. Mudstones greenish-gray, weathered, weathering cracks closed, iron hydroxides are present in the form of streaks. Brownish-gray limestones occur as interlayers capacity 0.3-1m, badly fractured.

Table 1 - Characteristics of Carboniferous deposits in the field of mine

Sweet	Power Formation	Sandstones,%	Sandy shale,%	Shale clay,%	Limestone,%	Coals,%
1	2	3	4	5	6	7
C13	350	44	48	5	2,9	0,1
C27	500	30	45	20	3,5	1,5
C26	300	40	40	16,4	2	1,6
C25	380	36	30	30	2,8	1,2
C24	250	30	45	23,2	0,8	1,1
C23	470	30	35	33	0,7	1,3

Tectonics

The mine is located in the southeastern part of the young wing Kalmius Toretskoy-basin, in the central part of the Donets-Makeevsky geologopromyshlennogo district. Tectonic due to location of a mine field in the transition zone of tectonically simple western part of the complex to the east.

The mine is located in the footwall of the regional wing of the French thrust, its boundary structural elements are: in the west - Frantsuzky thrust (supine wing), south-west - Mushketovsky thrust (hanging wall), in the east - Kalinin thrust (hanging wall) . Above thrusts are stepwise structure and characterized by the presence of powerful and crush zones of intense fracturing. In the zone of crushing and near tectonic contact developed small folding and tuck recovery and offshooting melkoamplitudnye violations.

From French genetically related thrusts Cross, Tsentrllny, Coke, Pastukhovsky, Ordzhonikidze. Kalinin thrust from its hanging wall is accompanied by a number of violations (one of them thrust D₂), which greatly complicate the tectonic structure of the estimated area in the eastern part of the mine field.

With Mushketovsky thrust associated with the formation Kalmiusskogo reset, reset "A», № 2.

It should be noted that the zones of tectonic disturbances are not stable and are subject to so-called "shifting of" in response to seismic crustal movements of varying intensity. Wherein the blocks divided tectonic faults move in vertical and horizontal directions relative to each other.

Carboniferous rocks in tectonic (geodynamic) zones fragmented fracture system in the same direction (within one zone) and these fragmentation zone extended to a greater depth, dividing the study area into several blocks.

In the north-eastern part of the reserve unit in the hanging wall of the Cross-thrust in the area of its junction with the French and Kalinino thrusts identified by the strata anticline h10, h8. By multiplicative forms tectonics relates sloping syncline in reservoir h5.

Disjunctive form tectonics presented disorders predominantly thrusting type, marked the development melkoamplitudnyh discharges [ 14 ].

Carboniferous

In the Middle Carboniferous sediments, related to the field of 54 mines coal seams and interlayers. 11 of them attain the conditioned power to the entire area or in individual areas.

In retinue C₂⁵ estimated layers k₅¹, k₅, k₄^2B, k₄. Very thin layers. A characteristic feature is the presence of erosion and thinning to broken power, which reduces their commercial value.

Most productive formation is C₂³. Contains 16 coal seams, of which 5 are the main reservoirs of industrial value (h₁₀, h₈, h₇, h₆, h₅). In addition to working coal seams within the field of mine are low-power, highly unstable formations. Their thickness 0,05-0,40 m

During exploration and appraisal of the mine field, it was found that the toxic elements in coal are sulfur and mercury [ 14 ]. Their content in some layers exceed the limits at which the formation of toxic substances exceeding MPC.

Average sulfur content of salable coal (for the period 1983 and 1990) was 2.3%, significantly higher than the allowable limit, and in 2014 was 3.2%. The mercury content far below the limit at which the compounds may be formed.

Arsenic, beryllium and fluorine below the limit at which the possible formation of toxic compounds concentrations exceeding the MAC, which allows them to be classified as potentially toxic.

Average and maximum level of potentially toxic elements (manganese, lead, nickel, vanadium, chrome, cobalt) below the level at which the formation of toxic compounds. Exceeding MPC.

Ecological characteristics

Air pollution

Emissions ventilation air flow when mining coal seams accompanied by the removal of the workings of carbon dioxide, methane, oxides of blasting, dust, condensation, heat and other impurities.

According to the literature [ 15 ] daily coal dust ejected from 0.1 to 0.18% of the total daily production of methane from 200 to 300 m3, dioxide emissions from 35 to 65 thousand m3, thousands of cubic meters of oxides produced during blasting operations from 180 thousand to 360 kJ of heat.

Conclusion outgoing air stream from the mine to them. MI Kalinin carried ventilation shafts with layers smolyaninovskoy Formation mainly trailers barrel. CO2 released into the atmosphere - 4608 m3/day; CO₂ - 944 640 m3/day; CH₄ - 13824 m3/day. There are a number of stationary pollution sources os

Table 2 - Characteristics of emission sources and emissions

Name of source selection centuries dimensions (height, diameter)	Centuries name	Number of substances from the source of the waste, emissions of all, tons / year	Amount of waste substances source into the atmosphere, t / year
1	2	3	4
1. Boiler tubes (45m, 1.5m)	Carbon monoxide Nitrogen oxide	46,68 20,64	46,68 20,64
2. Mehtseh, welding and gas cutting machines, pipe (2m, 1m)	Swar. aerosol Manganese oxides Carbon monoxide Nitrogen oxide	0,0223 0,0027 0,0058 0,00048	0,0223 0,0027 0,0058 0,00048
3. Stroytseh, woodworking. machines, pipe (10m, 0.5m)	Suspended solids	0,066	0,066
4. Warehouse inert dust suction (2m, 1m)	Suspended solids	0,0381	0,0381
5. Sorting, unloading rock (2m, 1m)	Suspended solids	0,790	0,790
6. Sorting, unloading coal (2m, 1m)	Suspended solids	1,195	1,195
7. However, loading the rock in the car	Suspended solids	0,294	0,294
8. Blacksmith shop, pipe (10m, 6m)	Blacksmith shop, bugle Suspended solids Carbon monoxide Nitrogen oxides Sulfur dioxide.	0,298 0,034 0,011 0,0158	0,298 0,034 0,011 0,0158
9. Blacksmith shop, side fan	Suspended solids Carbon monoxide	0,300 0,072	0,300 0,072
10. Blacksmith shop, aeration opening	Suspended solids Carbon monoxide	0,02 0,0063	0,02 0,0063
11. Locomotive garage, roof fan, trumpet	Aerosol caustics	0,0032	0,0032
12. However, the welding station	Welding fumes Manganese oxides Carbon monoxide Nitrogen oxides	0,100 0,0015 0,12 0,039	0,100 0,0015 0,12 0,039
13. Locomotive garage plot MDO	Welding fumes Manganese oxides Carbon monoxide Nitrogen oxides	0,19 0,0013 0,068 0,02	0,19 0,0013 0,068 0,02
14. Plot UKT (2m, 1m)	Welding fumes Manganese oxides Carbon monoxide Nitrogen oxides	0,0176 0,0022 0,00022 0,00022	0,0176 0,0022 0,00022 0,00022
15. Paintshop (2m, 1m)	Suspended vesch. White spirit Butyl Butanol Ethanol Toluene Etiltsellozol	0,18 0,03 0,0384 0,072 0,096 0,0384 0,0384	0,18 0,03 0,0384 0,072 0,096 0,0384 0,0384
16. Waste dump 75m	Suspended vesch. Carbon monoxide Nitrogen oxides Cerne. anhydride Hydrogen sulfide	102,92 3144,5 31,4 314,5 157,2	102,92 3144,5 31,4 314,5 157,2
17. Warehouse imported coal (2m, 1m)	Suspended vesch.	3,907	3,907
18. Warehousing and formed surfaces emergency warehouse	Suspended vesch.	3,335	3,335
19. The species complex with suction rocks into a hopper	Suspended vesch.	1,157	1,157
20. However, in the car	Suspended vesch.	0,46	0,46

Table 3 - Emissions of harmful substances into the atmosphere in the whole mine

Name harmful substances	Number of substances vydelyaemyx all sources, t/year	Quantity behaved cleaning	Total emitted into the atmosphere, tons/year
Suspended solids	116,60	1,1	115,5
Carbon monoxide	3191,48	-	3191,48
Sulfur dioxide	314,52	-	314,52
Hydrogen sulfide	157,2	-	157,2
Manganese oxides	0,02314	-	0,02314
Aerosol caustics	0,0032	-	0,0032
Nitrogen oxides	52,11	-	52,11
Whitespirit	0,03	-	0,03
Butyl	0,0384	-	0,0384
Butanol	0,072	-	0,072
Ethanol	0,096	-	0,096
Toluene	0,197	-	0,197
Acetone	0,0384	-	0,0384
Ethyl tsellozol	0,0384	-	0,0384
Total	3832,4465	1,1	3831,3465

At autopsy, the preparation and in the process of coal mining on the surface is given a significant amount of material that is stored on the surface in the dumps.

Temperature dumps formed under the influence of oxidative processes of sulfur impurities contained in coal dust and rock, as well as the temperature of the atmosphere. When burning heap of rocks formed an additional source of pollution and atmospheric origin. Combustion sources dumps are sources of intense steam and gas emissions. In the greenhouse gases methane, carbon oxides, sulfur, nitrogen, hydrogen sulfide and other compounds, and a variety of radionuclides. In places the gas jets on the surface of the heaps formed technogenic minerals, of which the most prevalent native sulfur and ammonia.

Soil

Upper layer section presents soil-vegetation layer, shown with black soil by plant roots, has a capacity of from 0 to 1.4 m and distributed in fragments.

In most of study area lie anthropogenic (bulk) soils presented a mixture of black earth, loam, slag, gravel, broken bricks, stones. So heaps posted overburden, sludge pit in sediments formed during the first clearing of the city pond. On the site there is a large number of landfills for household and construction waste. All these formations constitute anthropogenic layer of varying thickness, reaching a few tens of meters heaps.

On the industrial site of the mine waste dumps are located, which takes a considerable amount of storage host rocks. Kalinin mine waste dump is burning. Combustion sources dumps are sources of intense steam and gas emissions. In places the gas jets on the surface of the heaps formed technogenic minerals, of which the most prevalent native sulfur and ammonia.

Newly formed mineral forms are unstable and easily destroyed, form highly mobile ions that contribute to pollution of ground and surface waters. Set enrichment of local areas on the surface dumps thallium, antimony, mercury, lead, germanium, chlorine, sulfur, arsenic, bismuth, which, under the influence of acid precipitation may form easily movable compounds contaminating soil, groundwater and surface water.

In order to determine the status of soils was conducted Lithochemical sampling grid 500h500m. Samples were taken 20 points method "envelope". Samples were collected at each of two levels deep: 0,0-0,05 m and m 0,05-0,020

According to the results of testing along with heavy metals in soils and sediments found in the territory of the whole complex of defined organic compounds, ie formaldehyde, acetone, methanol, benzene, phenol, dibutyl disulfide, monoethanolamine, acetophenone, pyridine, toluene, styrene, chlorobenzene, xylene, butanol, dimethyl phthalate, thiocyanates, cyanides and oil.

Hydrosphere pollution

When mining operations and coal aquifers are opened resulting in a need in the organization for the purpose of drainage pumping mine water to the surface and its treatment prior to discharge to surface waters [ 15 ].

Mine dewatering system comprises: pumping mine water to the surface, horizontal three-piece horizontal tanks, disinfection liquid chlorine in the chlorination and then discharge into the pond in the gully Ignatievskaya doosvetlenie then the water from the pond flows into the city pond. In water samples collected in the underground workings of the mine and in places on the surface relief determined following organic compounds characteristic of technogenic load Donetsk-Makeevka promuzla acetone, acetophenone, difenilol propane, pyridine, methanol, toluene, chlorobenzene, styrene, butanol, xylene , ortho-xylene, metaparaksilol, cyanides, thiocyanates, oil.

Of the organic matter content is defined in the relevant phenol - from 0.001 to 0.021 dm 3, monoethanolamine - from 0.06 to 0.23 dm 3, dm 3 0,01-0,062 formaldehyde, benzene 0.01 0.02 dm 3, oil 0.01-0.25 dm 3.

Remaining organics contained in amounts below the threshold sensitivity of the method of determination.

Sources appearance in mine waters phenols can be considered:

1. Coal, its oxidation during production due to mechanical failure;
2. Vegetation, its expansion, delivery degradation products in groundwater, and with them in mine water;
3. Lubricants (oil emulsion), and their losses during use;
4. Air contaminated with phenols.

The causes of oil in mine waters are additives and emulsion are used as lubricants, various kinds of mineral oils and fuels, natural oil separation and biogenic carbons, which are products of microorganisms.

Availability in mine waters formaldehyde may be associated with coal mining at the analyzed company. Its presence in the important content can be associated with the work in paint shops and general development pressure on the area of Donetsk-Makeevka industrial center, including mine field, since formaldehyde is widely used in the manufacture of dyes, medicines, as a disinfectant, in the manufacture of plastics based on formaldehyde resins phenolics.

Research Methods

The paper is the following factual information:

• Geological maps, charts, plans, sections of the object, environmental reports;
• Laboratory studies of the composition and quality of groundwater (laboratory made "Standard") on the following parameters: suspended solids, COD, BOD, ammonia nitrogen, nitrite, nitrate, chloride, iron (total), salinity, sulfates, petrochemicals, phosphates. Samples are taken regularly from the sump inlet (before treatment) and the output (after cleaning), as well as in a pond in the gully Ignatievskaya, sample volume - 5 liters. Sampling was carried out four times a year.
• Field dual soil sampling points (on two levels: the soil and ground 0-0.05 0.05-0.20) and bind to a coordinate axis.

Primarily been systematized data from previous studies and conducted testing of soils and waters of the study area.

Soil sampling points (on two levels deep) were compared with the location ravine network dumps, industrial buildings, etc. Then, based on data on the MPC (mg / kg) (if absent, the regional background) coefficients were calculated concentrations of heavy metals. At the same time as the regional background I used the average contents of elements in soils Reserve Azov. When using regional background pollution was considered provided above this dual background. Further elements of the complex was calculated total pollution index for each sampling point.

Next the complex elements was calculated total pollution index for each sampling point.

Analysis of water sampling was conducted as follows:

• Has established by calculating the coefficient of concentration of substances for the entire study period. When calculating the values used PDS established for enterprises.
• Conducted study of changes in the values of the concentration of substances in space and time.

Were found statistical characteristics, correlation, regression equations are derived for the composition of mine waters and soils and subsoils in the target object. Calculated by the equation will determine the dependence of the content of the main components of mine waters and Soils from other indicators that are in it.

According to the research were built monoelementnye map the distribution of elements in soils territory, as well as the total soil contamination map to classify the territory of the general level of contamination. For the waters were constructed graphs of the content matter of the seasonal data and space throughout the chain mine water - Kalmiusskoe reservoir.

Data processing were used programs such as Microsoft Office Excel, SPSS, Surfer, MapINFO.

Current and expected outputs

A result of the work we have constructed monoelementnye map the spatial distribution of elements on two levels depths of soils: 0 - 0.05, 0.05 - 0.20 m Identified two groups of elements that differ in depth of maximum concentration. The first group contains elements which are characterized by concentration in the soil to a depth of 0.2 m: Ag, Ba, Cu. A second group of elements, which are concentrated at depths of 0.05 to 0.20 m The latter attributed: Pb, Nb, Mn, Sn, Zn.

Distribution of geochemical anomalies in area indicates their confinement to the main sources of pollution: waste dumps in the east and north of the site, the production site to the south. Notes and influence Valley Kalmius where geochemical anomalies are also marked elements. Such a distribution of elements in soils noted in many studies related to the assessment of soil pollution.

Particular interest is the distribution area of concentration Pb (Fig. 1). As can be seen from the figure, Pb anomalies exceedance in 2 and 3 times confined to the industrial site itself mine, in the zone of influence of mine shafts, as well as in the southern part of the map. In the southern part of the study area is the private sector and road transport to the heavy workload.

The north-west with a correlation anomalies dumps and pond. The award is the latest in a pond cascade ponds mine water.

Author were identified in soils and subsoils abnormal concentration of Ge. This element is a characteristic element for the formation h₁₀, mine being developed at the moment. Although this element is toxic, the study of its distribution and comparison with Spreading polluting elements can bind soil and water pollution from coal mining.