DonNTU   Masters' portal Institute of Mining and Geology Departement Zkk  

Abstract

Contents

Introduction

Nature protection from pollution is an urgent problem of our time, which in our country paid much attention.In this context, the problem of natural and waste water treatment is particularly important, since it is closely linked to the protection of water resources. Most methods of purification of natural and industrial waste waters, as well as ways of dewatering and compaction of different types based on the use of reagents.

In the past 20 years as a reagent becoming increasingly common water-soluble macromolecular substances - flocculants. Their use can improve the quality of treatment, increase productivity, water treatment plants, and some technological methods, such as centrifugation, generally can not be done without the use of flocculants[4].

Flocculants - is water-soluble high molecular weight compounds, which, when administered in disperse systems are adsorbed or chemically bound to the surface of the dispersed phase and combine particles in agglomerates (floccules), contributing to their rapid sedimentation. The history of high-molecular materials for purification of liquids from suspended impurities goes back to ancient times. Thus, even in 2000 BC India draw some plants containing natural polymers used for water purification, and in Ancient Greece natural polymer - egg white was used to lighten the wine. In XVIII-XIX centuries, natural polymers - gelatin and starch were used to clean fruit juices. Despite such a long history, the application of flocculation in industrial processes began in the period between the 30-mi and 50-ies of XX century. Flocculants used for the treatment of mine water from the particles of coal and clay, for the isolation and dewatering slag phosphate in obtaining uranium salts, to intensify the treatment of industrial waste water. But are widely used flocculants were from the mid 50's by the need to clean the increasing amounts of waste water and modernization of technological processes associated with the separation of solid and liquid phases. When increased demand flocculants could no longer be satisfied with natural polymers, began the introduction of organic synthetic (derivatives of starch and cellulose) and most synthetic polymers. Among the most widely used synthetic polymers and the application has received a group of polyacrylamide flocculants (PF)[5].

Most flocculants used in the present, it is organic synthetic polymers based on polyacrylamide, having different molecular weight and charge. Flocculants used for conditioning precipitation municipal wastewater, water from precipitation, galvanoshlamov, oil sludge etc. before mechanical dewatering centrifuges, filter - presses and other equipment, as well as to intensify the treatment of polluted wastewater.

Flocculants are available in the form of a granular powder with a particle size of 0.5 to 0.8 mm, are used in the form of dilute aqueous solutions with a concentration of 0.1-0.2%. The effectiveness of the working solution of flocculant depends on the validity of a solution.

Flocculant dissolution in a setup of different types of solution with stirring paddle or propeller mixer until smooth, viscous mass that are free of clots[1].

Flocculation - the process by which the adsorption interaction of the particle contamination of water with high-molecular substances (flocculants). During the interaction with the flocculant particles in the purified waste water, there is a process of flocculation to form aggregates (flakes, complexes), with three-dimensional structure. The mechanism of action of flocculants consists of three physical - chemical processes: adsorption of molecules on the surface of colloidal flocculation of particles, the formation of a network structure and adhesion molecules flocculent colloidal particles due to van der Waals forcesThe use of synthetic flocculants ensure high cleaning efficiency slurry water to produce clean water for technological needs of the plant, and sludge thickening. Under the action of flocculants between colloidal particles are formed three-dimensional structures capable of more rapid and complete separation of the liquid phase.

1. Purpose and objectives of the study

-The study of the dehydration products of enrichment and purification sludge treatment at the concentrators;

Research objectives:

1.Studied experimentally clarification sludge treatment using polymer flocculants type «Besfloc» - South Korean production company «KolonLifeScience, Inc».

2.Find innovative solutions related best circulating water in demand in the processing plant, the definition of quality flocculant having a low cost and high performance.

2. Justification themes and brief analysis of the issue

Polymer flocculants are widely used in the field of coal and ore. Flocculants known natural or synthetic chemicals that when injected into the dispersion system (eg ore slurry sludge) may form a mechanical connection between the particles of the solid phase and the cause, due to the destabilization of the system.

They are used in most systems, the separation of solid / liquid separation, increasing the deposition rate, improving the transparency of the clarified water, increasing the productivity of equipment, improving filtration efficiency and significantly reducing costs.

The use of synthetic flocculants ensure high cleaning efficiency slurry water to produce clean water for technological needs of the plant, and sludge thickening. Under the action of flocculants between colloidal particles are formed three-dimensional structures capable of more rapid and complete separation of the liquid phase[2].

Special series of high-flocculants will:

High-rate deposition;

-High performance thickeners, clarifiers, etc.;

-Stable operation of water and sludge in closed circuits of industrial sites factories;

-Concentrated foods with a high content of solids (300-800g / l);

-Low-flow flocculants.

And the use of flocculants in filtration processes provides:

-Best-cake porosity;

-Increase the yield of the cake;

-Reduce humidity;

-More transparency leachate;

-Cleaner eat cake;

-Increase in the average life of filter cloth;

-Increase the productivity of equipment[8].

Lowest possible cost of reagents provide the lowest cost for processing of mineral raw materials and the best results of flotation. Required reagent consumption is determined by laboratory flotation tests, states in semi-industrial and industrial environments[2].

Pic. 1. –Scheme of flocculant brand BESFLOC for wastewater treatment.


2.1 Justification information flocculant

Flocculants are called water-soluble macromolecular substances used to separate solids from liquids and images in the water and the coarse three-dimensional structure of the colloidal particles (aggregates, cereal, complexes), regardless of whether these particles are a distinct interface between the phases (quartz, clay material, metal hydroxides) or they are macromolecules, no such surface (proteins, humic substances). This definition covers all flocculants used for natural and waste water, as well as compaction and dewatering and sludge. Flocculants are used either alone or in combination with aluminum sulfate, ferric chloride, lime and other mineral reagents[7].

In the 30-50's flocculation for practical applications in many processes associated with the separation of solids from liquid, to separate particles of coal and clay from the mine water, in the technology of uranium ore, for clarification of industrial effluents in nonferrous metallurgy, in the potash , pulp and paper mills, cement factories, food processing and some other îáëàñòåé.Âûñîêîìîëåêóëÿðíûå flocculants are usually divided into three groups: the active silicic acid, synthetic organic polymers (polyacrylamide, polyoxyethylene, polyacrylate, polyethylene, etc.), based on the natural flocculants substances (starch, cellulose ethers, guar gum, chitosan, etc.). Synthetic macromolecular flocculants were much more widespread than flocculants of natural origin, as they are more efficient, selective, cheaper, better hranyatsya.Otlichitelnym sign of polymers, in particular, water-soluble flocculants, is chain-like, linear or branched structure of macromolecules. The polymers can be homogeneous (homo) and heterogeneous (copolymers), the number of monomer units can range 250-70000, and the total length of the molecular chain of up to 7.5 x 10 - 110h103 nm. Synthetic polymers are produced by polymerization or polycondensation of monomers or polymer-analogous transformations of existing polymers

2.2 Application of flocculants in the mining industry

Application of flocculants in the mining industry

Polymer flocculants are widely used in the field of coal and ore.

They are used in most systems, the separation of solid / liquid separation, increasing the deposition rate, improving the transparency of the clarified water, increasing the productivity of equipment, improving filtration efficiency and significantly reducing costs.

Sedimentation:

The use of synthetic flocculants ensure high cleaning efficiency of water to form a slurry of clean water for technological needs of the plant, and sludge thickening. Under the action of flocculants between colloidal particles are formed three-dimensional structures capable of more rapid and complete separation of the liquid phase. Special series of high-flocculants and coagulants will:

- A high deposition rate;

- High performance thickeners, clarifiers, etc.;

- Stable operation of water and sludge in closed circuits promploschadok factories;

- Concentrated products with high solids content (300-800g / l.)

- Low consumption of flocculants.

Filtering:

A wide range of polymer flocculants provide the best option for each type of material being filtered. Flocculants are widely used for the optimization of filtration products, processing flotation concentrate, concentrated sludge, waste concentration, etc. In the process of filtering the flocculated mass forms a uniform pore structure, which is dehydrated with greater efficiency.

The use of flocculants in filtration processes provides:

• Best cake porosity;

• increase in the yield cake;

• Reduce humidity;

• greater transparency of leachate;

• A clean eat cake;

• increase the average life filter cloth;

• Increase the productivity of equipment[8].

The use of flocculants Bestfloc:

- In utilities, energy and other industries for the intensification of potable and industrial water;

- In the utilities sector, metallurgy, machine and apparatus construction, and other industries for enhanced wastewater treatment processes, compaction of sediments and sludge dewatering;

- The mining industry for pulp bleaching process intensification, seals, filtration and mechanical dewatering of sludge and (or) of the product;

- In the pulp and paper industry to keep the small fibers and fillers in the volume formed by the pulp, to intensify the process of water treatment, wastewater treatment and sludge dewatering;

- In the chemical, petrochemical, oil and other industries for process intensification phase separation "solid-liquid", "liquid-liquid", "liquid - solid - liquid", including the separation of sludge;

- In oil and other industries for use as a thickener in the drilling fluid, binder and thickener in waterizolation compositions and systems of the higher oil recovery, to intensify the processes of cleaning mud from the cuttings[9].

Ðic.2. – Shop reagents. The Department of preparation of coagulant: a - with a dry storage; b - with a wet storage; 1 - soluble tank; 2 - pump pump the solution into the service tank; 3 - feed tank coagulant, 4 - pump dispenser, 5 - lifting mechanism; 6 - a warehouse.

3.1.Investigation of the process of clarification of circulating water

To improve the quality of sludge water and reducing the cost of cleaning the enterprises constantly tested and implemented in the production of the special technological measures and new reagents.

Currently, the search for effective and inexpensive reagents for water treatment is an important goal in solving the problem of the quality of circulating water in the workplace. Therefore, in the course of the pre-diploma practice, the purpose of which was to study processes of dehydration products of enrichment of clarification and sludge waste, the experimental investigation of the process of clarification of sewage waters with the use of polymeric flocculants type «Besfloc»- production of the South Korean «KolonLifeScience, Inc.», tests were carried out.

For approbation were taken 8 samples of high-molecular polymer flocculants brand «Besfloc» - Ê4000, Ê4020, Ê4032, Ê4034, Ê4041, Ê4043, Ê4045 and Ê4046 of different types:

- non-ionic foaming agents (Ê4000, Ê4020)

- anionic (Ê4032, Ê4034, Ê4041, Ê4043,Ê4045, Ê4046).

Ðic. 3.2 . – Animation of the process of deposition (volume 12 KB, 8 frames, the delay between frames 0.5 MS)

Methodology of research:

In the experimental study of the process of clarification of circulating water, you need the following equipment, devices, materials and reagents:

1. Tailings (waste) flotation.

2. Graduated cylinders with a capacity of 1000 cm3

3. Manual agitator - 1 PCs.

4. Stopwatch - 1 PCs.

5. Pipettes for reagents - 1 PCs.

6. Scales with against weights.

. Solutions of flocculants 0.15 per cent target: water solutions of flocculant «Bestfloc» Ê4000, Ê4020, Ê4032, Ê4034, Ê4041, Ê4043, Ê4045 and Ê4046.

Technique of execution of work:

1.Îòîáðàëè 9 samples flotation tails mass of 100 (120) g each.

2.Âûñûïàëè sample flotation tails in measuring cylinders (each in a separate).

3.Applied to the investigation of flocculants 2 cm3 /l.

4.measuring cylinders with water up to the mark of 1000 cm3.

5.IN dimensional cylinder manually with the help of mixing thoroughly mixed mixture of flotation tails with wate

6. After mixing of the mixture installed measuring cylinders on even ground and timed with a stopwatch. With the interval of time produced height measurement layer in the dimensional cylinder without adding flocculant, using a scale of graph paper.

7. In the remaining measuring cylinders after mixing added the preset number of one of the water and the mixture was mixed again.

8. Height measurement layer in the study of influence on the process of product produced through every 10-30 with.

The speed of lightening determined by the formula:

Vîñâ = Hi/ 1000 * ti ,

ãäå Vîñâ- the speed of lightening, m/s; Hi - height îñâåòëåííîãî layer, mm; ti - time clarification with.

The results of the study are listed in tab. 1 - 4

In the experimental study of the process of clarification of the results showed that the use of flocculants in the process of cleaning of circulating water gives undoubted positive effect as to accelerate the process of coagulation, and for improving the quality of clarified water. The findings suggest that the high speed of lightening has flocculating agent Ê4020, and the lowest - anionic flocculant Ê4045.

Pic.4 – To add a flocculant

Pic. 5 . – Dynamics of clarification of coal slurry with the use of flocculant

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