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Abstract

Pobokina L.P.

Theme of master's work: "The analysis resourse-reseving of know-hows and advancing of processes of waste utilization of foundry production on the mechanical engineering and metallurgical complex”

The scientific superviso: Rostovskiy Vladimir Ivanovich

E-mail: ukrlena@mail.ru





Actual work

The urgency by mine magister work of activity is encompass byed volume, that in our locale it is a lot of mechanical engineering and metallurgical plants, in which one there are foundry shops. As all know, that the iron and steel industry, is one of main sources of contamination of atmosphere, rock sphere, hydrosphere, and also biosphere, accordingly and foundry production also is a source of contamination. First of all a problem on clearing of lets made by foundry is actual and also problem on waste, which one will be derivated as a result of activity of foundry . Some part of waste is detrimental, and the warehousing it on polygons only is simple will harm to our environment, and it is not rationally reclaim. I in magisters work tender to use waste of foundry production, and detail it cupola dross, cupola dust, slime gas cleaning of devices, short-running ingots and metallical swaft, combat of refractories, lining from boards, spent forming mixes and bad ground. All this is secondary valuable raw, and can be reused or foundry production or in metallurgical production.


The purpose and problems

The purpose and problems: to learn ecological problems of foundry production, to analyze and to give an ecological estimation, to elaborate measures on catching dust and gases, by providing their clearing, to organize recycling of spent mixes, to offer versions of salvaging cupola of drosses, dust and slimes, to make economical calculation on replacement dust separation of the installations, and to make calculations on replacement of chalkstone converter by dross as the back product, to compound a heat balance, under the information of the research, conducted by us, on usage of converter dross in foundry production.


State-of-the-art Review of a condition of an environmental protection in foundry production

State-of-the-art Review of a condition of an environmental protection in foundry production in the given head I view the tendency of development of foundry production as a whole, is observed quantity of effluint and discharge, and also waste as a whole on Ukraine, Russia and abroad. Effluint according on foundry plant it is necessary from 5 up to 70 % of parasitic lets, drops, sinks, blades of mechanical engineering production, and in general effluints on a fraction of foundry production it is necessary 3 % of dust and 0,5 % of a carbon monoxide. For a way out of the crisis it is expedient to learn foreign experience. Rotary point in ecological policy of West has become conference of the United Nations on an environment. From now on in USA, Germanium, England, Austria began intensive transformation law an ecology, including in foundry production.


Окислительно-восстановительный процесс печи


Classifications of waste of foundry production and ways their salvaging

Classifications of waste of foundry production and ways their salvaging
In the given head I view waste of foundry production. At extension 1ton. Castings in atmosphere kg acts till 40-60. Dust, 200-300 kgs. White damp, 1-2 kgs. Oxide of azote and sulfur of 0,5-1,5 kgs. Phenolum, formic aldehydes, aromatic hydrocarbon, ammonia, Cyanidums. In water basin acts up to 3м3 of sewages, and in blades is removed up to 6t. Spent forming mixes. There are many ways of processing of waste. We have elaborated the most rational ways, which one are possible for applying on ours mechanical engineering and metallurgical plants. Metallurgical drosses - valuable raw for production of building materials. However these raw material resources will be used while unsufficiently. In our country the annual exit of drosses of ferrous metallurgy makes more than 70 mln ton. From this quantity will be used about 53 %, remaining goes in blades. In slag blades was accumulated over half-billion of tons of waste, and they take thousand hectares of useful grounds. Processing and usage of drosses not only will extend base of raw of production of building materials received from natural raw, but also refines her geographic accommodation, thus will diminish also distance of transportation. From replacement by building materials from drosses it is possible to receive economic effect in a national economy.


Отвалы отходов литейного производства

Effluint of foundry production.

Effluint of foundry production.
The greatest hazard introduce just dust and gases in connection with difficulty of their catching, rendering and deleting. And their quantity by production 1 ton of castings from steel or cast iron approximately makes, kg: dust - 50, oxide C(II)) 250, oxide S(II)) 1,5-2, hydrocarbon - 1. Besides a number of other parasitic gases, such as Phenolum, formic aldehyde, furfurol, acetone, benzole etc. is selected, total which one though is insignificant, however introduces risk because of their toxicity. Gases removed from the foundry equipment and ejectable in atmosphere, are contained dust consisting in basic from finely divided particle, the contents of free oxide which one S(IV)) reaches 60 %. For an improvement of working conditions in steel departments it is necessary to execute a complex of effluints, which one actuates improvement of know-how on all process stage, advancing of the equipment, intrusion effective dry gas cleaning of the installations. For satisfactory activity of shop ventilating it is necessary to establish filters and vibrators for a shaking of gratings. To beat out and to clean castings follows on the separately arranged segments equipped with exhaust ventilation. It is necessary to equip transport belts with special shelters.


Reactivations of spent mixes and processing of a metallical swaft

Processing of a metallical swaft and reactivation of spent forming mixes In total volume of waste of industrial production the considerable proportion is made by waste inclusive different metals in given section are esteemed: alloys, and also oxides of metals, swaft of foundry production. On relevance of return of addition agents of one of most claimed is processing of a swaft of instrument steels, inclusive significant amount deficient and expensive addition agents - tungsten, molybdenum, vanadium, cobalt. Under the data of activity the swaft, are at processing of parts from tool steels, makes 20-40 % from weight. For salvaging the indicated waste the different methods were tendered. For example, to processing of a doped swaft widely remelting in electric furnace boards with ingots. The foundry plant makes about 50 ton per one year steel and 30 ton per year of a pig-iron casting. This will be derivated about 40 ton. per year of spent forming mixes, which one are removed according to the agreement on Larinscyua waste poligon. The plate of accommodation of waste makes about 2500 grn/years. At storage of spent forming mixes on a waste tip takes place duste and pollution of the environment. For the solution of this problem it is offered to conduct reactivation of spent forming mixes, elemental composition which one, %: SіО2- -95; clay - 2; Fe2O3 - 1,5. After reactivation the quality of forming mixes should meet to quality of fresh mixes.


Получение стали


Usages convertor of dross in cupola blust

Metallurgical slags are important primary products for building materials manufacture. However, now these material resources are used insufficiently. Every year in our country the amount of slags increases. Now only 12 % of steel-smelting slag are used. Conversion and usage of slags not only enlarge a source of raw materials of building material manufacture, but also serve as charge raw. The slags make 70-85 % of all iron and steel melting wastes. Their conversion allows to increase an economic efficiency of metal manufacture and saves fluxes. Converter slag contains more than 80 % of useful components and it is also an important material for a metal conversion. Nowadays, the usage of converter slag for remelting of cast iron in blast cupola is of current importance in foundry. A slag-making in blast cupola is an inevitable and technically indispensable process for obtaining high-quality metal. In metallurgy the different fluxes are applied for creating of a specified slag conditions. Limestone, containing СаО 49-52 %, is used as a flux for remelting of cast iron in blast cupola. We have conducted commercial researches concerning the usage of Еnakievo Metallurgical Plant converter slags at Makeevka Tube-casting Plant. There were 3 working blast cupolas at this plant. Limestone of 30-90 mm fraction and fluor-spar were used as fluxes. Stone rate is 4-5 % of loading weight. Foundry and pig iron, 45 %-ferrosilicon, ferromanganese, ferrophosphorus, scrap steel have been used as stock. Foundry coke has been used as fuel. The percentage makeup of the limestone was the following: 1,43 SiO2; 2,32 Al2O3; 51,62 CaO; 0,63 MgO; 0,055 P; 0,01 S; 0,26 Fe. At the time of our researches we were testing cupola slag and cast iron during usage of limestone and converter slag. The conducted researches have shown that during usage of converter slag the melting operation became hotter, the temperature of cast iron and cupola slag rose and it became more free-running. In the metallurgy the heat balance of the process becomes better in a case of replacement limestone by converter slag. The results of calculated heat balance are the following:
- heat consumption for limestone heating up to the dissociation temperature is 1752,3 kJ;
- heat consumption for CaCO3 dissolution is 996,8 kJ;
- heat consumption for CaO heating up to the temperature 1573 K is 142,8 kJ;
- quantity of heat evolved from 0,44 kg of CO2 is 359,5 kJ.
The total quantity of heat consumption for 1 kg of limestone is 3251,4 kJ/kg. The quantity of heat for converter slag heating up to the temperature 1573 K is 1928,3 kJ/kg. This calculation shows that usage of converter slag is more profitable than usage of limestone because of less heat consumption. The researches at Makeevka Tube-casting Plant have shown that percentage of СаО in limestone and converter slag is almost equal. However, converter slag contains useful components for fusion such as МgO, МnО, Аl2O3, СаF2, Fе. Therefore converter slag is a complex flux for blast cupolas. In a case of replacement limestone by converter slag we reduce a price of production and introduce resource-saving technology. It will have a positive influence on environment and will reduce the quantity of converter slag wastes. Our heat balance confirms it. We would recommend this technology to the foundries where the blast cupolas are used.


Получение стали

List of sources

  1. Ростовский В.И.\ Конспект лекций по курсу "Экологическая безопасность"


  2. Титов Н.Д., Степанов Ю.А.. Технология литейного производства. Машиностроение, 1978. - 432с.


  3. Иванов Б.С. Охрана труда в литейном и термическом производстве. Москва: Металлургия, 1990. – 222с.


  4. Розенгарт Ю.И. Вторичные энергетические ресурсы в черной металлургии и их использование. Высшая школа. 1988, – 327с.


  5. Денисов С.И. Управление и утилизация пыли и газов. Москва: Металлургия, 1991.-300с.






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